You should finalize your itinerary before asking what pass to buy, because the response can change if you add destinations.
Unless you have a must reason to go immediately to Hiroshima, you could finish your tour of Tokyo first, then use a 7-day JR Pass for the rest of the country.
Example:
Day 1 - arrival, stay in Tokyo; you could buy a 72-hr subway pass
Day 2 to 4 - continue to stay in Tokyo.
Day 5 - activate JR Pass and go to Odawara, from Odawara you go to Hakone but that segment is not covered by JR Pass. Stay in Hakone.
Day 6 - Go to and stay in Osaka, JR Pass is valid from Odawara to Osaka.
Day 7 - Go to and stay in Miyajima (Hiroshima), JR Pass is valid.
Day 8 - Go to and stay in Kyoto, JR Pass is valid.
Day 9 & 10 - Continue to Stay in Kyoto. Take a day trip to Nara, using JR Pass.
Day 11 - Go back to Tokyo and airport, JR Pass is valid.
You can add a night in Hiroshima and delete one in Kyoto, or similar, etc.
Again, you need to decide what you want to do in Tokyo first, then decide if subway suits that need.
Subway pass:
https://www.tokyometro.jp/en/ticket/travel/index.html