Oct. 1 is the middle of the week on a Wednesday... Thatfs a normal weekday.
I suppose seats of Limited Express would not get fully reserved.
I wasn't sure how much time it would take to get through the sites. Which sites do you plan to visit?
If you go to Chuzenji area
(Chuzenji Temple, Kegon Waterfall, Lake Chuzenjiko, etc.)
in addition to Toshogu - Rinnoji area,
it would be in the evening that you come back.
The sun sets at 17:24 (5:24 pm).
I suggest you secure your seats
on a train departing between 5 and 6 pm.
If you come back much earlier to Tōbu-nikkō Station,
consult the ticket counter and check the vacancy in other trains.
- Tobu Railway: Limited Express trains
https://www.tobu.co.jp/en/express_info/Tōbu-nikkō {17:44}
--[Limited Express Spacia X 12]--
{19:35} Asakusa.
Tōbu-nikkō {17:24}
--[Limited Express Revaty Kegon 46]--
{19:15} Asakusa.
Tōbu-nikkō {16:33}
--[Local]--
{16:42} Shimo-imaichi {17:02}
--[Limited Express Spacia X 10]--
{18:45} Asakusa.
Tōbu-nikkō {16:20}
--[Limited Express Revaty Kegon 42]--
{18:15} Asakusa.
----
For your reference:
Alternatively you can take Local and Express (w/o eLimitedh) trains for the entire route.
These trains donft require a surcharge,
which means you can take them just with your Tobu Nikko pass.
Tōbu-nikkō {16:03}
--[Local]--
{17:42} Minami-kurihashi {17:53}
--[Express]--
{1845} Hikifune {1846}
--[Local]--
{18:51} Asakusa.